97374-02-2Relevant academic research and scientific papers
Synthesis of novel 1,2,3-triazolyl derivatives of pregnane, androstane and d-homoandrostane. Tandem "click" reaction/Cu-catalyzed d-homo rearrangement
Kotovshchikov, Yury N.,Latyshev, Gennadij V.,Lukashev, Nikolay V.,Beletskaya, Irina P.
, p. 3707 - 3720 (2014/06/09)
Copper-catalyzed 1,3-dipolar cycloaddition has been employed in the reaction of steroidal azides with various terminal alkynes. A number of novel 1,2,3-triazolyl derivatives of pregnane, androstane and d-homoandrostane were obtained in high yield (70-98%)
Effects of 16-Heterosubstitution on the Regiochemistry of the D-Homo Rearrangement
Bischofberger, Norbert,Walker, Keith A. M.
, p. 3604 - 3609 (2007/10/02)
The 16β-phenylthio-, 16β-phenylseleno-, and 16β-dimethylphenylsilyl-substituted 3β,17α-dihydroxy-5-pregnen-20-ones have been prepared by nucleophilic ring opening of 16α,17α-epoxysteroids in order to study the influence of the 16-substituent on the regioc
