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Tris[(2-hydroxyethyl)isocyanide]bis(triphenylphosphane)rhodium chloride is a complex organic compound with the chemical formula [Rh(C9H10N2O)3(P(C6H5)3)2]Cl. It is a rhodium-based catalyst that plays a significant role in various chemical reactions, particularly in the field of homogeneous catalysis. tris[(2-hydroxyethyl)isocyanide]bis(triphenylphosphane)rhodium chloride consists of a central rhodium atom coordinated to three (2-hydroxyethyl)isocyanide ligands and two triphenylphosphane ligands, with a chloride ion as a counterion. Its unique structure endows it with high catalytic activity and selectivity, making it valuable in the synthesis of various organic compounds, such as olefins, through processes like hydroformylation and carbonylation. The compound's stability and reactivity are influenced by the electronic and steric properties of the ligands, which can be fine-tuned to optimize its performance in specific reactions.

97385-60-9

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97385-60-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 97385-60-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,7,3,8 and 5 respectively; the second part has 2 digits, 6 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 97385-60:
(7*9)+(6*7)+(5*3)+(4*8)+(3*5)+(2*6)+(1*0)=179
179 % 10 = 9
So 97385-60-9 is a valid CAS Registry Number.

97385-60-9Downstream Products

97385-60-9Relevant academic research and scientific papers

Metal Complexes of Functional Isocyanides, X. On Hydroxyalkyl Isocyanides and Their Stabilization in Metal Complexes

Fehlhammer, Wolf Peter,Bartel, Klaus,Weinberger, Bernd,Plaia, Ulrike

, p. 2220 - 2234 (2007/10/02)

The hydroxyalkyl isocyanides CNnOH (n = 2 (1a), 3 (1d), 5 (1e)), CNCH(Et)CH2OH (1b), and CNCH2CH(Me)OH (1c) have been synthesized from N-(hydroxyalkyl)formamides by dehydration with equimolar amounts of phosgene in the presence of triethylamine, spectroscopically (IR, 1H, 13C NMR) characterized and introduced into metal complexes, which stabilize 1a - e in the open chain form.The OH group of coordinated hydroxy isocyanides can be esterified or substituted for Cl.Conversely, hydrolysis of CNCH2OC(O)Ph in a series of newly prepared metal complexes of this ligandto give isocyanohydrin (CNCH2OH) complexes has not been accomplished.

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