97399-14-9Relevant academic research and scientific papers
Iron(II) Halide Promoted Cyclization of Cyclic 2-Enynamides: Stereoselective Synthesis of Halogenated Bicyclic γ-Lactams
Yeh, Ming-Chang P.,Shiue, Yuan-Shin,Lin, Hsin-Hui,Yu, Tzu-Yu,Hu, Ting-Chia,Hong, Jia-Jyun
supporting information, p. 2407 - 2410 (2016/06/09)
A simple and mild process was developed for the highly stereoselective synthesis of halogenated bicyclic [4.3.0] and [3.3.0] γ-lactams, possessing four stereocenters, from easily available cyclic 2-enynamides. The reaction required only an inexpensive iron(II) halide under dry air and was tolerant of aryl, heteroaryl, and alkyl groups at the alkyne terminus.
SYNTHESIS OF PROTECTED ALLYLAMINES VIA PALLADIUM-CATALYZED AMIDE ADDITION TO ALLYLIC SUBSTRATES
Bystroem, Styrbjoern E.,Aslanian, Robert,Baeckvall, Jan-E.
, p. 1749 - 1752 (2007/10/02)
Palladium-catalyzed reaction of allylic substrates with sodium p-toluenesulfonamide leads to the N-allylic-p-toluenesulfonamides.The reaction takes place with retention of configuration at the allylic carbon.
