97399-25-2Relevant academic research and scientific papers
REDUCTION OF NITRO ALKENES BY A MODEL OF NAD(P)H
Nakamura, Kaoru,Fujii, Masayuki,Oka, Shinzaburo,Ohno, Atsuyoshi
, p. 523 - 526 (1985)
Carbon-carbon double bonds in α,β-unsaturated nitro compounds are reduced smoothly into the corresponding nitro alkanes by a model of NAD(P)H in benzene in the presence of silica gel.Other functional groups are inert under the reaction conditions.
A Highly Chemoselective Reduction of Conjugated Nitro Olefins with Hantzsch Ester in the Presence of Silica Gel
FUJI, Masayuki
, p. 4029 - 4036 (2007/10/02)
An effective system to reduce conjugated nitro olefins into the corresponding nitroalkanes is described.The system composed Hantzsch ester (HEH) and silica gel in benzene exerts high yield and excellent chemoselectivity under almost neutral conditions.Facile applications of the system to the syntheses of natural products are also described.
