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Oxo-bridged Compounds of Iodine(III): Syntheses, Structure, and Properties of μ-Oxo-bis
Gallos, John,Varvoglis, Anastasios,Alcock, Nathaniel W.
, p. 757 - 764 (2007/10/02)
The title compound has been prepared by using several approaches.It reacts with both strong bases and acids and is an oxidant.Its crystal structure has been determined from four-circle diffractometer data (R=0.043).The primary iodine geometry is T-shaped o>, with shorter I-O (bridge) than I-O (acid) .Secondary bonds have I...O of 2.929(8) Angstroem to 3.273(8) Angstroem.
