97411-44-4Relevant academic research and scientific papers
Synthesis of New N-Aminoaziridine Derivatives by the Addition of Dibenzyloxycarbonylaminonitrene to Olefins
Milcent, Rene,Guevrekian-Soghomoniantz, Marina,Barbier, Geo
, p. 1845 - 1848 (2007/10/02)
In order to study the ring expansion of N-aminoaziridines into N-amino-5-membered heterocycles, N-(dibenzyloxycarbonylamino)aziridines were synthesized.N,N-Dibenzyloxycarbonylhydrazine was prepared.It was then oxidized with lead tetraacetate to a new diacylaminonitrene.This nitrene was added to various olefins to give the corresponding N-protected aminoaziridines.Cleavage of the protecting groups was realized for one example.
