97416-71-2

Basic information

• Product Name: Benzene, [5-(methylthio)-1-pentenyl]-, (Z)-
• CAS NO: 97416-71-2
• Molecular Formula: C12H16S
• Molecular Weight: 192.325
• Mol File: 97416-71-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, [5-(methylthio)-1-pentenyl]-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [5-(methylthio)-1-pentenyl]-, (Z)-(97416-71-2)
• EPA Substance Registry System: Benzene, [5-(methylthio)-1-pentenyl]-, (Z)-(97416-71-2)

Safety Data

• Hazardous Substances Data: 97416-71-2(Hazardous Substances Data)

Upstream product

• 211427-69-9 1,3,4,5,6,11a-hexahydro-7E-2-benzothionine 
• 13042-80-3 3,4-dihydro-2H-thiopyran 
• 74-88-4 methyl iodide 

Relevant articles and documents

Novel chemical behaviour of a [2,3] sigmatropic rearrangement product of 2-phenyltetrahydrothiopyranium 1-methylide

1,3,4,5,6,11a-Hexahydro-7E-2-benzothionine 5, which is a [2,3] sigmatropic rearrangement product of 2-phenyltetrahydrothiopyranium 1-methylide 8, has been synthesized by reaction of 1-methyl-2-phenyltetrahydrothiopyranium triflate 3 with sodium amide in liquid ammonia or by the fluoride ion-induced desilylation of trans-2-phenyl-1-[(trimethylsilyl)methyl]tetrahydrothiopyranium perchlorate trans-7. Compound 5 is stable at room temperature and reverts to ylide 8 by ring-opening.