97423-82-0

Upstream product

• 154666-87-2 1,3,4,6-tetra-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranosyl azide 

Downstream Products

• 6205-69-2 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosyl azide 
• 111270-20-3 tri-O-acetyl-2-(toluene-4-sulfonylamino)-2-deoxy-β-D-glucopyranosyl azide 
• 114517-59-8 N-(3,4,6-tri-O-acetyl-2-amino-2-deoxy-β-D-glucopyranosyl)triphenylphosphine imide 
• 29847-23-2 2-N-acetylamido-2-deoxy-β-D-glucopyranosyl azide 
• 112656-74-3 N-(O¹-methyl-α-D-glucopyranose-2-yl)-toluene-4-sulfonamide 
• 1207847-32-2 3,4,6-tri-O-acetyl-2-deoxy-2-(4-methoxybenzylidenamino)-β-D-glucopyranosylazide 
• 1352639-90-7 C₄₄H₄₀N₂O₆P₂ 

Relevant academic research and scientific papers

Selective removal of 2,2,2-trichloroethyl- and 2,2,2- trichloroethoxycarbonyl protecting groups with Zn-N-methylimidazole in the presence of reducible and acid-sensitive functionalities

Activated zinc dust in the presence of N-methylimidazole in ethyl acetate or acetone at reflux or room temperature removes 2,2,2-trichloroethyl- and 2,2,2-trichloroethoxycarbonyl protecting groups while azido-, nitro-, chloro-, phenacyl-, and tert-butyl ester functionalities as well as double bonds remain intact.