97477-98-0Relevant academic research and scientific papers
Iodine(III)-Mediated Allylaton of Aromatic Compounds and Alcohols Using Allylmetal (Group IVb) Compounds
Ochiai, Masahito,Fujita, Eiichi,Arimoto, Masao,Yamaguchi, Hideo
, p. 41 - 47 (2007/10/02)
The reaction of allylmetal (group IVb) compounds with aromatic compounds and iodosylbenzene in the presence of BF3-Et2O afforded the corresponding allylation products.Allylation of alcohols was also carried out to give allyl ethers.The activation of iodosylbenzene by the coordination of BF3-Et2O was assumed to be one of the most important factors for the reaction.The involvement of the reactive allyliodine(III) compounds in these reactions is discussed.Keywords - hypervalent organoiodine compound, iodosylbenzene; allylsilane; allylgermane; allylstannane; allyliodine(III) compound
