97479-46-4Relevant academic research and scientific papers
Studies Dealing with the Alkylation--Rearrangement Reaction of Some Phenylthio-Substituted Allylic Sulfones
Padwa, Albert,Bullock, William H.,Dyszlewski, Andrew D.
, p. 955 - 964 (2007/10/02)
A series of 2-(phenylthio)-3-(phenylsulfonyl)alkenes are easily metalated with n-butyllithium, and the resulting carbanion is regioselectively alkylated by alkyl halides in the α-position to give β,γ-unsaturated sulfones in high yield.These substituted ph
Mass Spectral Rearrangements of 3-Arylsulphonyl-2-arylthiopropenes and N-(4'-Arylsulphonyl-2'-butynyl)-N-(4"-arylthio-2"-butynyl)anilines
Glaspy, P. E.,Hancock, R. A.,Thyagarajan, B. S.
, p. 281 - 287 (2007/10/02)
Under electron impact the title compounds undergo skeletal rearrangement in the addition to the anticipated modes of cleavage.The 3-arylsulphonyl-2-arylthiopropenes readily eliminate sulphur dioxide.Other modes of fragmentation include rearrangement to a
