97529-84-5Relevant articles and documents
A cross-metathesis approach to the synthesis of (+)-phomopsolide B
Reddy, D. Vasudeva,Sabitha, Gowravaram,Yadav
, p. 4112 - 4114 (2015/08/03)
Abstract The synthesis of phomopsolide B has been achieved using an olefin cross-metathesis (CM) reaction as key step. Two metathesis partners, enediol and 5-hydroxy vinyl lactone were prepared from l-ascorbic acid. This is the first report of using 5-hyd
Total Synthesis of Natural (+)-Phomopsolide B, an Antifeedant against Elm Bark Beetle
Noshita, Toshiro,Sugiyama, Takeyoshi,Yamashita, Kyohei,Oritani, Takayuki
, p. 740 - 744 (2007/10/02)
The total synthesis of natural (+)-phomopsolid B (2) is described.A 5,6-dihydro-2H-pyran-2-one framework was constructed by coupling chiral aldehyde 4 and 4-oxygenated enaminoester 5.The resulting 5,6-dihydro-4-pyrrolidyl-2H-pyran-2-one (3) was converted to natural (+)-phomopsolide B (2) in several steps.