97562-17-9

Upstream product

• 97562-15-7 (S)-4-Benzyloxy-3-hydroxy-2-methoxy-2-methyl-pentanoic acid methyl ester 
• 81445-44-5 (S)-2-(benzyloxy)propanal 
• 3587-60-8 Benzyloxymethyl chloride 
• 130050-98-5 methyl 4-O-benzyl-3-O-(benzyloxymethyl)-5-deoxy-2-C-methyl-2-O-methyl-L-ribonate 
• 130050-98-5 (S)-4-Benzyloxy-3-benzyloxymethoxy-2-methoxy-2-methyl-pentanoic acid methyl ester 

Downstream Products

• 97562-18-0 4-O-benzyl-3-O-(benzyloxymethyl)-5-deoxy-2-C-methyl-2-O-methyl-L-ribose 
• 97562-21-5 5-O-benzyl-4-O-(benzyloxymethyl)-2,6-dideoxy-3-C-methyl-3-O-methyl-L-ribohexose 
• 97562-19-1 (3R,4S,5S)-5-benzyloxy-4-(benzyloxy)methoxy-3-methoxy-3-methyl-hex-1-ene 
• 97562-20-4 5-O-benzyl-4-O-(benzyloxymethyl)-2,6-dideoxy-3-C-methyl-3-O-methyl-L-ribohexitol 

Relevant academic research and scientific papers

De novo synthesis of carbohydrates by stereoselective aldol reaction: L-cladinose.

Aldol reactions of methyl 2-methoxypropanoate (4), the corresponding ester of 2-methoxypropanoic acid with 4-methyl-2,6-di-(tert-butyl)phenol (13), and silylketene acetals 14 and 15 with (S)-2-(phenyl-methoxy)propanal (17) have been investigated. The lith

ACYCLIC STEREOSELECTION. 28. USE OF STEREOSELECTIVE ALDOL METHODOLOGY IN THE TOTAL SYNTHESIS OF CLADINOSE.

Reactions of (S)-2-benzyloxypropanal (4) with the lithium, magnesium, and zirconium enolates of methyl 2-methoxypropanoate (1) and with ketene acetals 2 and 3 have been studied and the stereostructures of the resulting products elucidated.The major stereo