97600-24-3Relevant articles and documents
STUDIES ON THE CONFORMATION OF 1-ARYL-1-NITROSOUREAS AND RELATED COMPOUNDS
Tanno, Masayuki,Sueyoshi, Shoko
, p. 1353 - 1359 (2007/10/02)
The carbon-13 nuclear magnetic resonance spectra of 1-aryl-3,3-dialkyl-1-nitrosoureas and related compounds were measured at about -40 degC, and their chemical shifts were assigned.The conformations of the N-nitroso compounds having the 1-aryl-1-nitrosoureido group were established through comparison with N-alkyl-N-nitrosoanilines, and the decomposition mechanism of 1-aryl-3,3-dialkyl-1-nitrosoureas is discussed on the basis of the results.Keywords - 1-aryl-3,3-dialkyl-1-nitrosourea; 1-aryl-1-nitrosourea; N-nitrosourea; N-nitrosoacetanilide; N-nitrosoaniline; triazene; nitrosyl radicals; E-Z conformation; (13)C-NMR