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Upstream product

• 1629-58-9 4-penten-3-one 
• 583-55-1 1-Bromo-2-iodobenzene 
• 15115-58-9 3-(2-bromophenyl)propionic acid 
• 925-90-6 ethylmagnesium bromide 
• 616-25-1 1-Penten-3-ol 
• 244205-40-1 (2-bromophenyl)boronic acid 

Relevant academic research and scientific papers

The palladium-catalyzed conjugate addition type reaction of 2-bromo-arylmercury compounds and 2-bromo-aryl iodides with α,β-enones: A new entry to 1-indanols

The palladium-catalyzed reaction of 2-bromoarylmercury compounds or of 2-bromophenyl iodide with α,β-enones gives conjugate addition type products which can be cyclized to 1-indanols in the presence of magnesium.

C-X (X=Br, I) bond-tolerant aerobic oxidative cross-coupling: A strategy to selectively construct β-aryl ketones and aldehydes

Using moelcular oxygen as the terminal oxidant, various aryl halide-containing β-aryl ketones and aldehydes can be synthesized directly from readily available allyic alcohols and boronic acids via palladium-catalyzed oxidative cross-coupling reactions. The dual roles of copper, including electron-carrier and Lewis acid functions, are supposed to be critical for the high reactivity and selectivity of this aerobic oxidative coupling transformation. Copyright

Asymmetric palladium-catalyzed intramolecular α-arylation of aldehydes

(Chemical Equation Presented) Phoxy ligand: The first catalytic method for the asymmetric palladium-catalyzed intramolecular α-arylation of α-branched aldehydes was developed (see scheme). This process is distinguished by the high yields and enantioselectivities that can be obtained, making this protocol a useful synthetic tool for further applications.

O-arylation versus C-arylation: Copper-catalyzed intramolecular coupling of aryl bromides with 1,3-dicarbonyls

The copper-catalyzed intramolecular coupling of aryl bromides with 1,3-dicarbonyls via a six-membered ring closure was examined. With CuI (10 mol %) as the catalyst, N,N′-dimethylethylenediamine as the ligand, and Cs2CO3 as the base,