97675-17-7

Basic information

• Product Name: 1-(2,2-Dichloro-1,1,2-trifluoro-ethylsulfanyl)-4-methoxy-benzene
• CAS NO: 97675-17-7
• Molecular Weight: 291.121
• Mol File: 97675-17-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(2,2-Dichloro-1,1,2-trifluoro-ethylsulfanyl)-4-methoxy-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2,2-Dichloro-1,1,2-trifluoro-ethylsulfanyl)-4-methoxy-benzene(97675-17-7)
• EPA Substance Registry System: 1-(2,2-Dichloro-1,1,2-trifluoro-ethylsulfanyl)-4-methoxy-benzene(97675-17-7)

Safety Data

• Hazardous Substances Data: 97675-17-7(Hazardous Substances Data)

Upstream product

• 76-13-1 1,1,2-Trichloro-1,2,2-trifluoroethane 
• 56830-32-1 potassium p-methoxybenzene thiolate 

Relevant articles and documents

Chemistry of Halogenoperfluoroalkanes> Synthesis of Fluorinated Ethers and Thioethers via Radical or Anionic Intermediates

Condensation of bromotrifluoromethane with potassium thiophenoxides in DMF is performed under pressure (2-3 atm) in a glass apparatus.Inhibition by nitrobenzene shows that a SRN1 mechanism is involved in the formation of aryl trifluoromethyl sulfides.Dichlorodifluoromethane itself reacts through a similar process to give aryl chlorodifluoromethyl sulfides.Condensation of 1,1,2-trichlorotrifluoroethane with potassium thiophenoxide or phenoxide occurs even in the presence of nitrobenzene.The formation of aryl 2,2-dichloro-1,1,2-trifluoroethyl sulfides or ethers can be explained by a chain carbanionic mechanism.