97690-89-6Relevant academic research and scientific papers
Synthesis of elaiolide and halichoblelide aglycone
O'Neil, Gregory W.,Phillips, Andrew J.
, p. 1413 - 1415 (2019)
A synthesis of two structurally related macrodiolides representing the aglycone of natural products elaiophylin and halichoblelide is described. The key transformation for both is a Ti(II)-mediated (silyloxy)enyne cyclization, generating a new methyl ster
