97772-77-5Relevant academic research and scientific papers
Controlled introduction of allylic group to chlorosilanes
Li, Zhifang,Cao, Xiaojun,Lai, Guoqiao,Liu, Jinhua,Ni, Yong,Wu, Jirong,Qiu, Huayu
, p. 4740 - 4746 (2006)
Allylation of chlorosilanes has been achieved with allylsamarium bromide, especially in a controlled manner. Thus allylation of trisubstituted chlorosilanes (R3SiCl) afforded a variety of aryl, aralkyl, and alkenyl substituted allylsilanes. Dichlorosilanes (R2SiCl2) can either afford monoallylated silanes or diallylated silanes depending on the amount of allylsamarium bromide used. Similarly, trichlorosilanes (RSiCl3) can selectively afford mono-, di-, and tri-allylation products. Finally, perchlorosilane (SiCl4) was allylated stepwise and the corresponding silanes containing one, two, three or four allylic groups, respectively, were obtained in satisfactory yields.
Selective mono- and di-allylation and allenylation of chlorosilanes using indium
Li, Zhifang,Yang, Chenjun,Zheng, Hongfang,Qiu, Huayu,Lai, Guoqiao
scheme or table, p. 3771 - 3779 (2009/02/08)
Allyl and allenyl groups have been introduced into silicon systems by the allylation and allenylation of chlorosilanes using allyl bromide or propargyl bromide with indium. The allylation of chlorosilanes afforded a variety of aryl, aralkyl, and alkenyl substituted allylsilanes. By applying this method, the reactions of 1-bromo-3-methylbut-2-ene, 3-bromo-2-methylprop-1-ene and 3-bromobut-1-ene with chlorosilanes also proceed smoothly to give regioselectively allylic rearrangement products in good yields. Mediated by indium, dichlorosilanes (R2SiCl2) and trichlorosilanes (RSiCl3) can either afford monoallylated silanes or diallylated silanes depending on the amount of allyl bromide and indium used.
5-ORGANO-1,5-PHOSPHA-SILABICYCLOOCTANE-SYNTHESE UND REAKTIONSVERHALTEN
Issleib, K.,Kuehne, U.,Krech, F.
, p. 367 - 374 (2007/10/02)
The synthesis of the title compounds from the corresponding organo trichlorsilanes as well as the reactivity of these compounds by reactions with methanol, phenylisothiocyanate, phenylisocyanate, sulfur and other compounds are described.The solvolysis of
