97780-98-8Relevant articles and documents
Copper-Catalyzed Redox-Triggered Remote C-H Functionalization: Highly Selective Formation of C-CF3 and C-O Bonds
Li, Taotao,Yu, Peng,Lin, Jin-Shun,Zhi, Yonggang,Liu, Xin-Yuan
supporting information, p. 490 - 494 (2016/06/01)
A Cu-catalyzed remote sp3 C-H/unactivated alkenes functionalization reaction for the concomitant construction of C-CF3 and C-O bonds was described. An 1,5-H radical transfer involving an sp3 C-H bond adjacent to a nitrogen atom and an α-CF3-alkyl radical intermediate derived from unactivated alkenes was observed and demonstrated to proceed via the radical process. C-CF3 formation/1,5-H radical shift/remote functionalization of sp3 C-H bond.
Phosphine-catalyzed remote β-C-H functionalization of amines triggered by trifluoromethylation of alkenes: One-pot synthesis of bistrifluoromethylated enamides and oxazoles
Yu, Peng,Zheng, Sheng-Cai,Yang, Ning-Yuan,Tan, Bin,Liu, Xin-Yuan
supporting information, p. 4041 - 4045 (2015/03/30)
An unprecedented phosphine-catalyzed remote β-C-H functionalization of amine derivatives triggered by trifluoromethylation of an alkene with Togni's reagent was disclosed. This reaction proceeded through the highly selective and concomitant activation of
A NOVEL PHOTOSUBSTITUTION OF DICYANOBENZENES BY ALLYLIC AND BENZYLIC SILANES
Mizuno, Kazuhiko,Ikeda, Munehiro,Otsuji, Yoshio
, p. 461 - 464 (2007/10/02)
The photosubstitution of o- and p-dicyanobenzenes by allylic and benzylic silanes in acetonitrile occurred efficiently, giving the corresponding mono-allylated and benzylated cyanobenzenes.