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Dualistic Behaviour of Carbamoyl Isothiocyanates, II. Determination of their Equilibrium with Thiocarbamoyl Isocyanates
Goerdeler, Joachim,Bartsch, Hans-Juergen
, p. 2294 - 2299 (2007/10/02)
Various carbamoyl isothiocyanates, in part new, were prepared.The equilibrium R2N-CO-NCS R2N-CS-NCO was proven at elevated temperatures, its equilibrium constants were determined at various temperatures in different solvents by IR spectroscopy.The equilibrium shows considerable dependence on the constitution, mainly on the steric effects of R.
