97797-56-3Relevant academic research and scientific papers
Protium-deuterium exchange of cyclic and acyclic alkanens in dilute acid medium at elevated temperatures
Werstiuk, Nick Henry,Timmins, George
, p. 530 - 533 (2007/10/02)
A modification of the high temperature - dilute acid (HTDA) method for deuterium labelling of aromatic compounds has been applied to the H-D exchange of a number of cyclic and acyclic alkenes.Cyclopentene, cyclohexene, cyclododecene, and tetramethylethylene have been completely exchanged in excellent yield. 1-Methylcyclopentene and 1-methylcyclohexene have also been perdeuterated and cycloheptene and cyclooctene partially labelled but require spinning band distillation or preparative glpc for separation from rearrangement products.A variety of C5-C8 acyclic alkeneshave also been treated under HTDA conditions.
