97805-15-7

Upstream product

• 90056-26-1 (1S,2R,5S)-2-methyl-5-(1-methylethenyl)-1-((tetrahydropyran-2-yl)oxy)-3-cyclohexene 
• 97691-01-5 C₂₁H₃₀O₃Se 
• 90056-25-0 (1S,2S,3R,5S)-2-methyl-5-(1-methylethenyl)-3-(phenylseleno)-cyclohexanol 
• 97691-00-4 (1S,2S,3R,5S)-2-methyl-5-(1-methylethenyl)-3-(phenylseleno)-cyclohexanol tetrahydropyranyl ether 
• 76339-71-4 (2S,3R,5S)-2-methyl-5-(1-methylethenyl)-3-(phenylseleno)-cyclohexanone 
• 127853-80-9 (2S,3S,5S)-3-Hydroxy-2-methyl-5-(1-methylethenyl)cyclohexanone 
• 2244-16-8 (S)-p-mentha-6,8-dien-2-one 

Downstream Products

• 90129-47-8 (4S,5R)-4-hydroxy-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enone 
• 710313-34-1 (1S,2S,3S,5R,6R)-3-Benzyloxy-5-isopropenyl-2-methyl-7-oxa-bicyclo[4.1.0]heptane 

Relevant academic research and scientific papers

Synthetic studies of the HIV-1 protease inhibitive didemnaketals: Stereocontrolled synthesis of an ester side chain

The stereocontrolled synthesis of the C1-C8 portion, the ester side chain of the HIV-1 protease inhibitive didemnaketals from the ascidian Didemnum sp., has been carried out through 15 steps starting from (S)-carvone as the chiral template. This approach involved the diastereoselective construction of three conjoint chiral centers by intramolecular chiral inducement, and generation of allylic alcohol intermediate through a key Grob fragmentation reaction.

Highly Efficient Conversion of (-)-Carvone to (+)-5β-Hydroxycarvone

(-)-Carvone has been efficiently transformed into (+)-5β-hydroxycarvone (1), which is expected to play an important role as a potential precursor or as a chiral template in the synthesis of natural products.Both hydroxy selenides 4 and 5, obtained by the