97815-03-7

Upstream product

• 112399-50-5 2-bromo-5-fluorobenzyl bromide 
• 603-35-0 triphenylphosphine 
• 452-63-1 2-Bromo-5-fluorotoluene 

Downstream Products

• 97814-85-2 bromo-4-fluoro-1-methyl-13-pentahelicene 
• 97814-69-2 3-[(Z)-2-(2-Bromo-5-fluoro-phenyl)-vinyl]-6-methyl-phenanthrene 
• 97838-47-6 3-[(E)-2-(2-Bromo-5-fluoro-phenyl)-vinyl]-6-methyl-phenanthrene 
• 97814-72-7 3-Bromo-6-[(Z)-2-(2-bromo-5-fluoro-phenyl)-vinyl]-phenanthrene 
• 1206795-71-2 2-[2-(2-bromo-5-fluorophenyl)ethenyl]naphthalene 
• 203-12-3 benzo[ghi]fluoranthene 
• 97814-70-5 6-[(Z)-2-(2-Bromo-5-fluoro-phenyl)-vinyl]-phenanthrene-3-carboxylic acid methyl ester 
• 97814-71-6 3-[(Z)-2-(2-Bromo-5-fluoro-phenyl)-vinyl]-phenanthrene 
• 1309570-77-1 4-(2-bromo-5-fluorophenethyl)phenol 

Relevant academic research and scientific papers

Enantioselective palladium-catalyzed dearomative cyclization for the efficient synthesis of terpenes and steroids

A novel enantioselective palladium-catalyzed dearomative cyclization has been developed for the efficient construction of a series of chiral phenanthrenone derivatives bearing an all-carbon quaternary center. The effectiveness of this method in the synthe

Palladium(0)-catalyzed arylative dearomatization of phenols

The palladium-catalyzed arylative dearomatization of phenols to yield spirocyclohexadienone products in good to excellent yields has been developed. Preliminary results demonstrate that the formation of the spirocyclic all-carbon quaternary center can be accomplished with high levels of enantiocontrol (up to 91% ee).

Highly efficient fluorine-promoted intramolecular condensation of benzo[c]phenanthrene: A new prospective on direct fullerene synthesis

Various functional groups have been tested as alternative promoters of the intramolecular condensation of benzo-[c]phenanthrene under flash vacuum pyrolysis conditions. Methyl and fluorine functionalization were found to be promising approaches. Unexpectedly high selectivity was observed in the cyclization of fluorinated benzo[c]phenanthrenes. The mechanism for the condensation reaction and the advantages of fluorine as a promoter for the rational synthesis of fullerenes are discussed. Wiley-VCH Verlag GmbH & Co. KGaA.

HELICENES : SYNTHESE PHOTOCHIMIQUE DE FLUORO-1-PENTAHELICENES

1-Fluoropentahelicene and substituted derivatives have been synthesized by the photocyclodehydrogenation of 1,2-di(2-naphtyl) ethylenes (1) and 3-styrylphenanthrenes (2).In two cases (1a and 2d) the photocyclisations gave rise to benzo perylenes (7, 8, 23, 24) a reaction involving either the loss (8, 24) or the fluorine atom.The 1H-NMR spectra are described.