97852-35-2Relevant academic research and scientific papers
Novel reaction course of thiiranes to vinyloxiranes: Reaction of benzyne with thiiranes and aldehydes
Okuma, Kentaro,Qu, Yuxuan,Nagahora, Noriyoshi
, p. 1294 - 1300 (2021/07/19)
Reaction of 2 molar amount of 2-(trimethylsilyl)phenyl triflate with thiiranes and aldehydes in the presence of CsF afforded vinyloxiranes in one-pot operation. Reaction of benzyne with thiiranes gave the corresponding alkenyl phenyl sulfides, which furth
Syntheses and synthetic applications of stannylated allylic alcohols
Kazmaier, Uli,Lucas, Simon,Klein, Manuela
, p. 2429 - 2433 (2007/10/03)
Allenyl carbinols undergo regioselective hydrostannation in the presence of MoBl3, a catalyst originally developed for the hydrostannation of alkynes, giving rise to allyl stannanes. These allyl stannanes can easily be converted into useful synthetic building blocks such as allyl iodides or vinyl epoxides.
Chloroallyl Anion: Highly Regio- and Diastereoselective α-Addition of Chloroallyl Zinc Reagent to Carbonyl Compounds
Mallaiah, K.,Satyanarayana, J.,Ila, H.,Junjappa, H.
, p. 3145 - 3148 (2007/10/02)
The chloroallyl zinc reagent generated insitu by deprotonation of allyl chloride in the presence of lithium diisopropylamide and zinc chloride undergoes highly regio- and diastereoselective α-addition to carbonyl compounds to give syn chlorohydrins which
DIALKYLTELLURONIUM ALLYLIDE AS A NOVEL REAGENT FOR SYNTHESIS OF Α,Β-UNSATURATED EPOXIDES
Osuka, Atsuhiro,Suzuki, Hitomi
, p. 5109 - 5112 (2007/10/02)
Reaction of dialkyltelluronium allylide with aldehydes gave rise to α,β-unsatirated epoxides with moderate Z-selectivity and in good yields.
Reaction of 3-Chloroallyltrimethylsilane with Acid Chloride and Exploitation of a New Regioselective Synthesis of αβ-Unsaturated Epoxide
Ochiai, Masahito,Fujita, Eiichi
, p. 4369 - 4372 (2007/10/02)
α-Chloro-βγ-unsaturated ketone (2) was synthetized from the reaction of 3-chloroallyltrimethylsilane (1) with acid chloride.The ketone was converted into αβ-unsaturated epoxide (3) regioselectively in good yield via reduction with NaBH4 or LiAlH4 followed
