97964-71-1Relevant articles and documents
NAD(P)H and Acetyl-CoA Models: Part II - Reaction of Diphenylnitrosamine and Methylphenylnitrosamine with 1,1'-Diacetyl-1,1',4,4'-tetrahydro-4,4'-bipyridine
Juneja, T. R.,Gupta, R. L.,Swarnakumar, K. G.,Pathak, D. P.
, p. 193 - 195 (2007/10/02)
Diphenylnitrosamine (1a) and methylphenylnitrosamine (1b) have been treated with 1,1'-diacetyl-1,1',4,4'-tetrahydro-4,4'-bipyridine (DTB) to understand the pattern arising as a result of biomimetic transfer of hydride and acetyl cation from the reagent.A number of products have been isolated and characterized.The interesting feature of the reaction is the -N-N=O cleavage in 1 to give hydroxylamine derivative, O-acetylacetohydroxamic acid (5).