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97965-02-1

3-<1'-methyl-3'-(diphenylphosphinoyl)prop-2'-enyl>cyclohexanone is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 97965-02-1 Structure

  • Basic information

    1. Product Name: 3-<1'-methyl-3'-(diphenylphosphinoyl)prop-2'-enyl>cyclohexanone
    2. Synonyms:
    3. CAS NO:97965-02-1
    4. Molecular Formula:
    5. Molecular Weight: 352.413
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 97965-02-1.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 3-<1'-methyl-3'-(diphenylphosphinoyl)prop-2'-enyl>cyclohexanone(CAS DataBase Reference)
    10. NIST Chemistry Reference: 3-<1'-methyl-3'-(diphenylphosphinoyl)prop-2'-enyl>cyclohexanone(97965-02-1)
    11. EPA Substance Registry System: 3-<1'-methyl-3'-(diphenylphosphinoyl)prop-2'-enyl>cyclohexanone(97965-02-1)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 97965-02-1(Hazardous Substances Data)

97965-02-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 97965-02-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,7,9,6 and 5 respectively; the second part has 2 digits, 0 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 97965-02:
(7*9)+(6*7)+(5*9)+(4*6)+(3*5)+(2*0)+(1*2)=191
191 % 10 = 1
So 97965-02-1 is a valid CAS Registry Number.

97965-02-1Downstream Products

97965-02-1Relevant articles and documents

Aprotic Conjugate Addition of Allyllithium Reagents Bearing Polar Groups to Cyclic Enones. 1. 3-Alkylallyl Systems

Binns, Malcolm R.,Haynes, Richard K.,Katsifis, Andrew G.,Schober, Paul A.,Vonwiller, Simone C.

, p. 5411 - 5423 (2007/10/02)

The conjugate addition of lithiated (E)- and (Z)-oct-2-enyl sulfoxides and phosphine oxides, but-2-enyl sulfoxides, phosphine oxides and phosphonates, and 3,3-dimethylallyl and allyl sulfoxides to cyclic enones has been examined.The E and Z carbanions react in highly diastereoselective fashion with five-membered cyclic enones to deliver respectively syn and anti vinylic sulfoxides, phosphine oxides, and phosphonates.Hexamethylphosphoric triamide has no regiochemical influence on these reactions.The regiochemical and stereochemical outcomes of these reactions are rationalized in terms of planar lithiated reagents in which Li+ is bound to oxygen attached to sulfur or phosphorus of the polar group and a 10-membered "trans-decalyl"- or "trans-fused chair-chair"-like transition-state model in which the lithiated reagent adopts an endo orientation over one face of the enone such that for the reagent, the 3-alkyl group is pseudoequatorial, and for the Z, pseudoaxial.

THE DIASTEREOSPECIFIC APROTIC CONJUGATE ADDITION REACTIONS OF CARBANIONS DERIVED FROM ALLYLIC SULFOXIDES AND ALLYLIC PHOSPHINE OXIDES.

Binns, Malcolm R.,Haynes, Richard K.,Katsifis, Andrew A.,Schober, Paul A.,Vonwiller, Simone C.

, p. 1565 - 1568 (2007/10/02)

The title carbanions undergo conjugate addition to cyclic enones in THF to deliver vinylic sulfoxides and vinylic phosphine oxides as single diastereomers.

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