98006-86-1Relevant academic research and scientific papers
UNPRECEDENTED GAMMA-SELECTIVE MICHAEL ADDITION OF TIN(II) DIENOLATES TO ACYCLIC α,β-UNSATURATED KETONES
Stevens, Rodney W.,Mukaiyama, Teruaki
, p. 851 - 854 (2007/10/02)
Tin(II) dienolates were found to react exclusively at the gamma carbon with acyclic α,β-unsaturated ketones in the Michael sense.Either acyclic 1,7-diketones or 2-cyclohexenol derivatives could be obtained in moderate to excellent yields by appropriate ch
