98033-52-4Relevant academic research and scientific papers
CHLORINATION OF 2-H-PENTACHLORO-1,3-BUTADIENE
Kaberdin, R. V.,Nikolaeva, E. E.,Potkin, V. I.,Ol'dekop, Yu. A.
, p. 448 - 451 (2007/10/02)
The chlorination of 2-H-pentachloro-1,3-butadiene with gaseous chlorine in the presence of antimony pentachloride at 10-15 deg C was investigated.It was shown that the chlorine adds at positions 1,2 and 3,4 with the formation of a mixture of 1,1,1,2,3,4,4-heptachloro-3-butene and 1,1,3,3,4,4,4-heptachloro-1-butene in a ratio of 72.8:27.2 respectively.The action of 100percent nitric acid on 1,1,3,3,4,4,4-heptachloro-1-butene gave β,γ,γ,γ-tetrachlorocrotonic acid.
