98039-08-8

Upstream product

• 84247-11-0 6-O-benzyl-3,5-dideoxy-1,2-O-isopropylidene-3,5-di-C-methyl-β-L-idofuranose 
• 84247-04-1 methyl 3,6-dideoxy-3-C-methyl-α-D-glucopyranoside 
• 84247-16-5 3,5-dideoxy-1,2-O-isopropylidene-3-C-methyl-5-C-methylene-α-D-xylo-hexofuranose 
• 84247-07-4 6-O-acetyl-3-deoxy-1,2-O-isopropylidene-3-C-methyl-α-D-glucofuranose 
• 84247-06-3 Toluene-4-sulfonic acid (R)-2-hydroxy-2-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-ethyl ester 
• 78822-31-8 3,6-dideoxy-1,2-O-isopropylidene-3-C-methyl-α-D-glucofuranose 
• 78785-26-9 5,6-Anhydro-3-desoxy-1,2-O-isopropyliden-3-C-methyl-α-D-gluco-hexofuranose 
• 78785-27-0 3,5-dideoxy-1,2-O-isopropylidene-3,5-di-C-methyl-β-L-idofuranose 
• 78853-51-7 3,5,6-trideoxy-1,2-O-isopropylidene-3-C-methyl-5-C-methylene-α-D-xylo-hexofuranose 
• 72353-13-0 3,6-dideoxy-1,2-O-isopropylidene-3-C-methyl-α-D-xylo-hexofuranos-5-ulose 
• 53872-67-6 1,2:5,6-di-O-isopropylidene-3-C-methyl-3-deoxy-α-D-glucofuranose 
• 98039-04-4 6-O-benzyl-3,5-dideoxy-1,2-O-isopropylidene-3,5-di-C-methyl-α-D-gulofuranose 
• 72353-13-0 3,6-dideoxy-1,2-O-isopropylidene-3-C-methyl-β-L-lyxohexofuranos-5-ulose 
• 98039-03-3 3,5-dideoxy-1,2-O-isopropylidene-3,5-di-C-methyl-α-D-gulofuranose 

Downstream Products

• 84247-24-5 1-O-benzyl-2,4,7-trideoxy-2,4-di-C-methyl-D-glycero-L-ido-heptitol 
• 98039-05-5 (2R,3S,4R)-5-benzyloxy-3-formyloxy-2,4-dimethylpentanal 

Relevant academic research and scientific papers

Chiral Synthesis of Polyketide-derived Natural Products. Part 5. Synthesis of a Chiral Segment Corresponding to the C-1-C-5 Unit of Erythromycin A from D-Glucose

As a right-hand segment with three consecutive chiral centres corresponding to the C-1-C-5 unit of erythromycin A (1), (2S,3R,4S)-3,5-isopropylidenedioxy-2,4-dimethylpentanal (32) was synthesized from D-glucose (5) by application of MPM (4-methoxybenzyl)

A CHIRAL SYNTHESIS OF 3,5,7-TRI-O-BENZYL-1,4,6-TRIDEOXY-4,6-DI-C-METHYL-keto-L-ido-2-HEPTULOSE, A SYNTHETIC SEGMENT OF THE C-1 - C-6 PORTION OF ERYTHRONOLIDE A

3,6-Dideoxy-1,2-O-isopropylidene-3-C-methyl-α-D-glucofuranose (9) was prepared from methyl 4,6-O-benzylidene-3-deoxy-3-C-methyl-α-D-glucopyranoside via 3-deoxy-1,2-O-isopropylidene-3-C-methyl-α-D-glucofuranose (5) in 61percent yield.The key intermediates,