98039-10-2

Upstream product

• 69832-48-0 ((3aR,5S,6R,6aR)-tetrahydro-2,2-dimethyl-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)furo[2,3-d][1,3]dioxol-6-yl)methanol 
• 824-94-2 p-methoxybenzyl chloride 

Downstream Products

• 86654-52-6 (2S,3R,4R)-1-benzyloxy-3-hydroxy-4-hydroxymethyl-5-(4-methoxybenzyloxy)-2-methylpentane 
• 98039-14-6 Methanesulfonic acid 3-benzyloxy-2-[(3aR,5R,6R,6aR)-6-(4-methoxy-benzyloxymethyl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl]-propyl ester 
• 98039-19-1 (2S,3R,4S)-1-benzyloxy-3-hydroxy-4-(4-methoxybenzyloxymethyl)-2-methyl-5-(p-tosyloxy)pentane 
• 98039-11-3 3-deoxy-1,2-O-isopropylidene-3-C-(4-methoxybenzyloxymethyl)-6-O-(tosyl)-α-D-allofuranose 
• 98039-13-5 6-O-benzyl-3-deoxy-1,2-O-isopropylidene-3-C-(4-methoxybenzyloxymethyl)-α-D-ribo-hexofuranos-5-ulose 
• 86654-50-4 3-Benzyloxy-2-[(3aR,5R,6R,6aR)-6-(4-methoxy-benzyloxymethyl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl]-propan-1-ol 
• 98039-12-4 6-O-benzyl-3-deoxy-1,2-O-isopropylidene-3-C-(4-methoxybenzyloxymethyl)-α-D-allofuranose 
• 86654-51-5 (3aR,5R,6R,6aR)-5-(2-Benzyloxy-1-methyl-ethyl)-6-(4-methoxy-benzyloxymethyl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole 
• 98039-17-9 (2R,3R,4ξ)-5-benzyloxy-3-formyloxy-2-(4-methoxy-benzyloxymethyl)-4-methylpentanal 
• 86654-48-0 5,6-anhydro-3-deoxy-1,2-O-isopropylidene-3-C-(4-methoxybenzyloxymethyl)-α-D-allofuranose 
• 86654-53-7 (2S,3R,4R)-1-benzyloxy-3-hydroxy-5-(4-methoxybenzyloxy)-2,4-dimethylpentane 
• 86654-49-1 5-C-(benzyloxymethyl)-3,5,6-trideoxy-1,2-O-isopropylidene-3-C-(4-methoxybenzyloxymethyl)-α-D-ribo-hex-5-enofuranose 
• 86654-52-6 (2R,3R,4R)-1-benzyloxy-3-hydroxy-4-hydroxymethyl-5-(4-methoxybenzyloxy)-2-methylpentane 
• 113956-99-3 ethyl (5R)-hydroxy-4(R)-(4-methoxybenzyl)oxymethyl-2-methyl-2(E)-heptenoate 

Relevant academic research and scientific papers

TOTAL SYNTHESIS OF TYLONOLIDE, THE AGLYCONE OF THE 16-MEMBERED RING MACROLIDE TYLOSIN, FROM D-GLUCOSE. SELECTIVE APPLICATION OF MPM AND DMPM PROTECTING GROUPS FOR HYDROXY FUNCTIONS

Segments i (C11-C17) and ii (C1-C10), synthesized from D-glucose by employing some stereoselective reactions and benzyl-type protecting groups, were esterified and cyclized to the 16-membered enone , which was readily converted to tylonolide, the aglycone

Chiral Synthesis of Polyketide-derived Natural Products. Part 5. Synthesis of a Chiral Segment Corresponding to the C-1-C-5 Unit of Erythromycin A from D-Glucose

As a right-hand segment with three consecutive chiral centres corresponding to the C-1-C-5 unit of erythromycin A (1), (2S,3R,4S)-3,5-isopropylidenedioxy-2,4-dimethylpentanal (32) was synthesized from D-glucose (5) by application of MPM (4-methoxybenzyl)