98094-69-0Relevant articles and documents
Tetracyclic triterpenes. VIII. The skeletal rearrangement of 3β-acetoxy-9α,11α-epoxy-5α-lanostan-7-one: 13- and 10-methyl group migration
Paryzek, Zdzislaw,Widra, Roman
, p. 1280 - 1286 (2007/10/02)
The boron trifluoride etherate catalyzed rearrangement of 3β-acetoxy-9α, 11α-epoxy-5α-lanostan-7-one (1) in acetic acid anhydride resulted in formation of 19(10->9β)abeo compounds 2 and 4 along with 18(13->12β)abeo compound 5, as the major product.These structures are supported by spectral data and chemical transfomations.The possible mechanism of the rearrangements is discussed.