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SYNTHESIS OF NITROCYCLOPROPYLPHENYL ARYL SULFIDES
Shabarov, Yu. S.,Veselovskaya, S. V.,Saginova, L. G.
, p. 481 - 484 (2007/10/02)
The nucleophilic substitution of halogen in the series of (nitrohalogenophenyl)cyclopropanes by the action of sodium p-thiocresolate was studied.In N-methylpyrrolidone at 165 deg C (2,4-dibromophenyl)cyclopropane gives (2,4-di-p-tolylthiophenyl)cyclopropane.In hexamethylphosphorotriamide (2-chloro-6-nitrophenyl)cyclopropane and (2,4-dibromo-6-nitrophenyl)cyclopropane undergo substitution of the halogen atoms by the SC6H4CH3-p group at 20 deg C.
