98155-60-3Relevant academic research and scientific papers
Gemini guests with spacers of various length drive the self-assembling of supramolecular capsules in water at neutral pH differently
Sgarlata, Carmelo,Arena, Giuseppe,Sciotto, Domenico,Bonaccorso, Carmela
, p. 696 - 702 (2013/11/19)
Water-soluble homodimeric capsules resulting from the electrostatic and hydrophobic interactions between a tetracationic calixarene receptor and gemini guests having the negatively charged ends separated by a (-CH2-) n (n = 2-6) spac
Synthesis and characterization of binuclear Zn(II)-cyclen complexes bridged by α,ω-bis(4-methylphenoxy) alkanes
Wan, Fuxian,Li, Changcheng,Jiang, Lin,Li, Ying
, p. 2085 - 2096 (2013/02/23)
A series of novel α,ω-bis(4-methylphenoxy) alkane functionalized cyclen ligands were synthesized by the nucleophilic substitution reaction of 1,4,7-tris(tert-butyloxycarbonyl)-1,4,7,10-tetraazacyclododecane and α,ω-bis(4-bromomethylphenoxy) alkanes. The corresponding dimeric Zn(II)-cyclen complexes were obtained by reaction of these ligands with Zn(ClO4)2·6H2O. Ligands and complexes were characterized by FT-IR, 1H NMR, and elemental analysis. Springer Science+Business Media B.V. 2012.
Initial structural studies of charged receptors that bind to inorganic phosphate anion and to an anionic phospholipid found in bacterial membranes
Koralegedara, Manjula B.,Aw, Hong W.,Burns, Dennis H.
experimental part, p. 1930 - 1933 (2011/06/24)
ITC titration studies of a family of bis-ammonium receptors based upon a scaffold of two bis-linked phenol rings show that several of the receptors bind to both dihydrogenphosphate and phosphatidylglycerol anions in a similar binding motif. Thermodynamic
Process for producing di(aryloxy)alkane
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, (2008/06/13)
A process for producing a high quality di(aryloxy)alkane with a high yield by the use of readily commercially available materials, without using any particular solvent or agent and by means of a simple operation and a general apparatus is provided, which process comprises subjecting a halogenated alkane of the formula (II) wherein X and Y each represent a halogen atom and A represents a lower alkylene group, and a phenol of the formula (III) STR1 wherein R1 to R5 each are same or different, represent hydrogen, halogen, lower alkyl, lower alkoxy, carboxylic acid salt, acyl or nitro group, and may form a ring in conjunction of two adjacent groups, to condensation reaction in the presence of an alkali in an aqueous medium to form a di(aryloxy)alkane of the formula (I) STR2 and is characterized (i) by carrying out the condensation reaction in a molar ratio of the compound of the formula (II): the phenol of the formula (III): the alkali in terms of monovalent base of 1:1.5 to 3.0:1.5 to 3.0; or (ii) by carrying out the condensation reaction of the above (i) and adjusting the quantity of the aqueous medium phase after completion of the reaction can be 35% or less based on the oily phase; or (iii) by carrying out the condensation reaction of the above (i), feeding at least the alkali among the reaction components with progress of the reaction and adjusting the quantity of the aqueous medium phase as described in the above (ii).
