98235-83-7Relevant academic research and scientific papers
Tetraisopropoxyzirkonium and Tri-isopropoxyaluminium in Regioselective Reduction of Pyrimidinones
Hoseggen, Tom,Rise, Frode,Undheim, Kjell
, p. 849 - 850 (2007/10/02)
The Meerwein-Ponndorf-Verley reduction of pyrimidin-2(1H)-ones using tetraisopropoxyzirconium or tri-isopropoxyaluminium leads to exclusive formation of the 3,4-dihydro isomer.The former reducing agent is found to be the more effective.
Regioselectivity in The Reductive Formation of Dihydro-5-halo-2(1H)-pyrimidinones
Rise, Frode,Undheim, Kjell
, p. 195 - 202 (2007/10/02)
5-Chloro-2(1H)-pyrimidinones are reduced by lithium tri-tert-butoxyaluminum hydride to dihydropyrimidinones.Pyrimidines with a substituent capable of conjugation gave the dihydro isomer which has its double bond in conjugation with this substituent.In the
