98239-59-9Relevant academic research and scientific papers
Addition of Phthalimidonitrene to Tetrasubstituted Cyclopentadienones
Narasimhan, K.,Rajakumar, P.
, p. 141 - 143 (2007/10/02)
The aziridines (3, 7, 10) obtained by the cycloaddition of phthalimidonitrene (1) to indanocyclone (2), phencyclone (6) and acecylone (9) undergo cycloreversion when treated with hydrazine hydrate, through the intermediacy of N-aminoaziridines.Aziridine (3) when treated with p-TsOH gives (5).Thermolysis of the aziridines (3) and (10) furnishes the rearranged products.
