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Triphenylphosphonium-triphenylphosphanetrichloronickelate(II) is a complex chemical compound with the formula [Ph3P][NiCl4(PPh3)]. It consists of a triphenylphosphonium cation (Ph3P) and a triphenylphosphane-trichloronickelate(II) anion (NiCl4(PPh3)). The compound is formed by the coordination of a triphenylphosphane (PPh3) ligand to a nickel(II) center, which is already coordinated to four chloride ions. This results in a square planar geometry around the nickel atom. Triphenylphosphonium-triphenylphosphanetrichloronickelate(II) is an example of a transition metal complex with a phosphorus-containing ligand, and it is of interest in the field of organometallic chemistry and coordination chemistry due to its unique structure and potential applications in catalysis and materials science.

98240-76-7

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98240-76-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 98240-76-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,8,2,4 and 0 respectively; the second part has 2 digits, 7 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 98240-76:
(7*9)+(6*8)+(5*2)+(4*4)+(3*0)+(2*7)+(1*6)=157
157 % 10 = 7
So 98240-76-7 is a valid CAS Registry Number.

98240-76-7Relevant academic research and scientific papers

Syntheses, Crystal and Molecular Structure of Ionic Nickel Complexes with Phosphanes in the Cationic and Anionic Part

Brenndoerfer, Maria,Brune, Hans Albert,Debaerdemaeker, Tony,Hemmer, Reinhard

, p. 357 - 362 (2007/10/02)

The syntheses of five new nickel-II-complexes of the type (R,R' = C6H5, n-C4H9, C6H11, C5H9, and R = C6H5, R' = C6H11) are described.The structure of the compound was determined by X-ray analysis.The crystals are monoclinic; space group P21/n with the lattice parameters a = 18.180(5), b = 18.842(4), c = 11.173(3) Angstroem and β = 107.12(6) deg; Z = 4. - Key words: Ionic Nickel Phosphane Complexes

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