98370-14-0Relevant academic research and scientific papers
Coordination Compounds of Organometallic Bases of Group IV Elements. Part-IX
Narula, Suraj P.,Shankar, Ravi,Kapur, Neeta
, p. 925 - 927 (2007/10/02)
The reactions of anilino/2-fluoroanilino/2,4-difluoroanilino/benzylamino/n-butylaminomethylbis(2,2,2-trifluoroethoxy)/tris(2,2,2-trifluoroethoxy)/tri-n-propoxysilanes in petroleum ether with SnCl4 and TiCl4 in the same solvent at -15 to -5 deg give solid compounds of composition RnSi(NHR')4-n.xMCl4, where R=CF3CH2O, CH3CH2CH2O, or CH3; R'=C6H5, C6H4F, C6H3F2, C6H5CH2, or n-C4H9; n=0, 1 or 2; x=1,2 or 3; and M=Sn or Ti.These compounds have been characterised by elemental analyses, infrared and 1H and 19F nmr spectra as well as ligand exchange reactions.The novel feature of these reactions is the formation of compounds of tetrakis(organoamino)silanes on reaction with organoaminotris(2,2,2-trifluoroethoxy)-silane with the Lewis acids.
Studies on Silicon-Nitrogen Compounds: Part V - Preparation and Characterisation of Some Substituted Organoaminoalkoxysilanes
Narula, Suraj P.,Kapur, Neeta,Shankar, Ravi,Mittal, Satish,Chodha, Arun,Kumar, Suniti
, p. 112 - 114 (2007/10/02)
Benzylamino/n-butylamino/2-chloroanilino/2,4-difluoroanilino/2-fluoroanilino/4-methylanilino-bis(2,2,2-trifluoroethoxy)methyl/bis(2,2,2-trifluoroethoxy)n-propoxy/tris(2,2,2-trifluoro-ethoxy)/tri-n-propoxy-silanes as well as bis(2-chloroanilino)/(2-fluoroa
