98370-25-3Relevant academic research and scientific papers
Coordination Compounds of Organometallic Bases of Group(IV) Elements: Part XI-Reactions of N,N'-(Phenyl/o-chlorophenyl/p-methylphenyl/benzyl/diethyl)-1,1-di-n-propoxy/n-butoxy-silanediamines with Tin(IV) and Titanium(IV) Chlorides at -10 deg C
Narula, Suraj P.,Kapur, Neeta,Shankar, Ravi,Chodha, Arun,Malhotra, Rajesh
, p. 519 - 522 (2007/10/02)
The title reactions in 1:1 molar ratio in petroleum ether (40-60 deg) afford adducts having rearranged bases with composition where R = C3H7 or n-C4H9; R' = C6H5CH2, o-ClC6H4 or p-CH3C6H4; n = 0 or 1; and x = 2 or 3 as evidenced by elemental analyses, IR and PMR spectral data as well as base exchange reactions.Filtrates of these reactions after keeping at room temperature for 48-72 hr, give solid complexes of the type in each case.The reaction with the tertiary amines such as N,N'-diethyl-1,1-di-n-propoxy/di-n-butoxysilanediamine form normal 1:1 adducts 2*MCl4> and no base rearrangement is observed.A tentative mechanism of the disproportionation reactions is proposed.
Studies on Silicon-Nitrogen Compounds: Part V - Preparation and Characterisation of Some Substituted Organoaminoalkoxysilanes
Narula, Suraj P.,Kapur, Neeta,Shankar, Ravi,Mittal, Satish,Chodha, Arun,Kumar, Suniti
, p. 112 - 114 (2007/10/02)
Benzylamino/n-butylamino/2-chloroanilino/2,4-difluoroanilino/2-fluoroanilino/4-methylanilino-bis(2,2,2-trifluoroethoxy)methyl/bis(2,2,2-trifluoroethoxy)n-propoxy/tris(2,2,2-trifluoro-ethoxy)/tri-n-propoxy-silanes as well as bis(2-chloroanilino)/(2-fluoroa
