98539-88-9Relevant academic research and scientific papers
Hexakis(2,4,6-triisopropylphenyl)cyclotristannoxane -A molecular diorganotin oxide with kinetically inert Sn-O bonds1
Beckmann, Jens,Jurkschat, Klaus,Rabe, Stephanie,Schuermann, Markus
, p. 2413 - 2419 (2001)
The single-crystal X-ray structure analysis of hexakis(2,4,6-triisopropylphenyl)cyclotristannoxane, cyclo-[(2,4,6-i-Pr3-C6H2)2SnO] 3 (1), is reported and reveals this compound to contain an almost planar six-membered ring. Redistribution reactions of 1 with cyclo-(t-Bu2SnO)3 and t-Bu2SiCl2, respectively, failed and indicate an unusual kinetic inertness of the Sn-O bonds in 1 as compared to related mo-lecular diorganotin oxides containing less bulkier substituents. The redistribution reaction of cyclo-(t-Bu2SnO)3 with cyclo-(t-Bu2SnS)2 leads to an equilibrium involving the trimeric diorganotin oxysulphides cyclo-t-Bu2Sn(OSnt-Bu2)2S (2a) and cyclo-t-Bu2Sn(SSnt-Bu2)2O (2b). WILEY-VCH Verlag GmbH, D-69451 Weinheim, 2001.
Attempted synthesis of a transition-metal stannaphosphene complex
Rodi, A. Kandri,Ranaivonjatovo,Escudie,Kerbal
, p. 157 - 169 (2007/10/03)
Fluoro-, chloro- and bromostannylphosphines (8-10) complexed on phosphorus by tungsten pentacarbonyl have been synthesized by reaction between lithium mesityl(tungsten pentacarbonyl)phosphide 4 and the corresponding dihalo(diisityl)tin (isityl: 2,4,6-triisopropylphenyl). Reaction of 8 with tert-butyllithium afforded the stable lithium fluorostannylphosphide 11. Addition of Me3SiCl or MgBr2 to 11 gave the corresponding chloro- and bromoderivatives 14 and 15. Similar compounds 16 and 17 were obtained from 9 and 10 and DBU. 11, 14, 15, 16 and 17 present a large 1JSnP coupling constant (2099.0 to 2151.4 Hz) indicating a partial Sn-P double bond.
