98669-68-2Relevant academic research and scientific papers
Derivate von 4,5-Dihydroxypyridonen durch Ringerweiterung
Stachel, Hans-Dietrich,Wiesend, Bruno,Kreiner, Christine
, p. 1413 - 1418 (2007/10/02)
The epimeric bromohydrins 13/14 as well as their ethers 5/6 rearrange in the presence of silver ions to the 5-hydroxypyridones 15 or their ketals 9 respectively.With the bromohydrin ethers 5/6a and b this transformation is effected also with sodium methox
Reactions of 5-Bromoalkylidene-3-pyrrolin-2-ones,1
Stachel, Hans-Dietrich,Poschenrieder,Hermann
, p. 1692 - 1696 (2007/10/02)
The title compounds 1 react with sodium methoxide to give 5--3-pyrrolin-2-ones 2 by substitution and to yield 5-hydroxy-2-pyridones 3 by ring enlargement.The relative amounts of the products depend on the substituents and the alko
