98753-99-2

Upstream product

• 98753-98-1 (4RS,5SR; E)-5-diphenylphosphinoyldec-2-en-4-yl nitrobenzoate 
• 98753-98-1 (4RS,5RS; E)-5-diphenylphosphinoyldec-2-en-4-yl nitrobenzoate 
• 96302-64-6 (4RS,5RS;E)-5-diphenylphosphinoyldec-2-en-4-ol 
• 19259-70-2 n-hexyldiphenylphosphine oxide 
• 96302-64-6 (4RS,5SR;E)-5-diphenylphosphinoyldec-2-en-4-ol 

Downstream Products

• 96302-81-7 (2RS,5SR; E)-5-diphenylphosphinoyldec-3-en-2-ol 
• 96302-81-7 (2RS,5RS; E)-5-diphenylphosphinoyldec-3-en-2-ol 
• 98754-03-1 (2E,4Z)-5-diphenylphosphinoyldeca-2,4-diene 
• 98754-02-0 (2E,4E)-5-diphenylphosphinoyldeca-2,4-diene 

Relevant academic research and scientific papers

Stereochemical Control (E/Z and syn/anti) by the Diphenylphosphinoyl Group in the Synthesis of Allylic Alcohols by Allylic Rearrangement and by 1,4-Diastereoselective Reduction of Enones

Allylic rearrangement of substituted 2-hydroxyalk-3-en-1-yl(diphenyl)phosphine oxides to 4-hydroxyalk-2-en-1-yl(diphenyl)phosphine oxides can be performed with total regio- and reasonable stereochemical control.Alternatively, the reduction of substituted

STEREOCONTROLLED SYNTHESIS OF δ-HYDROXY ALLYLIC PHOSPHINE OXIDES BY ALLYLIC ESTER TRANSPOSITION

The title compounds (3) were synthesised by stereospecific rearrangement, controlled by the Ph2PO group, from single isomers of the Horner-Wittig adducts (1).