98754-01-9Relevant academic research and scientific papers
STEREOCONTROLLED SYNTHESIS OF δ-HYDROXY ALLYLIC PHOSPHINE OXIDES BY ALLYLIC ESTER TRANSPOSITION
McElroy, Andrew B.,Warren, Stuart
, p. 1677 - 1680 (1985)
The title compounds (3) were synthesised by stereospecific rearrangement, controlled by the Ph2PO group, from single isomers of the Horner-Wittig adducts (1).
Stereochemical Control (E/Z and syn/anti) by the Diphenylphosphinoyl Group in the Synthesis of Allylic Alcohols by Allylic Rearrangement and by 1,4-Diastereoselective Reduction of Enones
Clayden, Jonathan,Collington, Eric W.,Elliott, Jason,Martin, Stephen J.,McElroy, Andrew B.,et al.
, p. 1849 - 1860 (2007/10/02)
Allylic rearrangement of substituted 2-hydroxyalk-3-en-1-yl(diphenyl)phosphine oxides to 4-hydroxyalk-2-en-1-yl(diphenyl)phosphine oxides can be performed with total regio- and reasonable stereochemical control.Alternatively, the reduction of substituted
