98771-39-2Relevant academic research and scientific papers
Synthesis and Properties of Bromo(methyl)- and Iodo(methyl)(organylthio)gallanes
Hoffmann, Gerhard G.
, p. 335 - 342 (2007/10/02)
The reaction between dibromo- or diiodo(methyl)gallane and the trimehylsilyl sulphides (CH3)3SiSR (R = CH3, C2H5, n-C3H7, i-C3H7, Ph, CH2Ph) have been investigated.Halo(methyl)(organylthio)gallanes are formed.These compounds and their chloro analogues can also be obtained by the reactions between the dihalo(methyl)gallanes and the corresponding leaddi(thiolates) in the molar ratios 2:1, or from the halo(dimethyl)gallanes and free thiols.Some physical and chemical properties of the new compounds are given, and the tentative mechanisms of these reactions are discussed.Syntheses of methylgalliumdiiodide and dimethylgalliumhalides via trimethylgallane and galliumtrihalides or methylgalliumdihalides are described. - Key words: Organogallium Derivatives, Trimethylsilyl Sulphides, Leaddi(thiolates), Synthesis, Properties
