98830-70-7Relevant academic research and scientific papers
One-pot synthesis of aryl sulfones from alcohols
Murakami, Teiichi,Furusawa, Kiyotaka
, p. 479 - 482 (2002)
A one-pot synthesis of aryl sulfones from primary alcohols is described. Alcohols were treated with N-bromosuccinimide and triphenylphosphine, followed by addition of sodium arenesulfinate with a catalytic amount of tetrabutylammonium iodide to afford the aryl sulfones in good to high yields.
Hydrogen Iodide Strategy for One-Pot Preparation of Allylic Azides, Nitriles, and Phenyl Sulfones from Allylic Alcohols
Kanai, Takaya,Kanagawa, Yoshinori,Ishii, Yasutaka
, p. 3274 - 3277 (2007/10/02)
Hydrogen iodide, HI, cleanly generated in situ from Me3SiCl/NaI and water in acetonitrile under mild conditions, was found to be an attractive reagent for the conversion of allylic alcohols into allylic iodides which serve as good allylic cation equivalent.Thus, treatment of allylic alcohols with Me3SiCl/NaI/H2O, followed by the substitution with N3-, CN-, and PhSO2- ions in the same flask produced the corresponding allylic compounds bearing azide, cyano, and phenyl sulfonyl functionalities in fair yields.This method provides a useful procedure for the preparation of allylic compounds from easily available allylic alcohols.
