98856-95-2Relevant academic research and scientific papers
ON THE CONVERSION OF ARABINO- AND RIBOFURANOSYL METHYL GLYCOSIDES TO THEIR 1-O-ACETYL DERIVATIVES
Cimpoia, Alex R.,Hunter, Patricia J.,Evans, Colleen A.,Jin, Haolun,Breining, Tibor,Mansour, Tarek S.
, p. 1115 - 1120 (2007/10/02)
Improved conditions for the acetolysis of methyl 2,3,5-tri-O-benzyl-α- and β-L-arabinofuranosides and 2,3,5-tri-O-benzoyl-α- and β-L-ribofuranosides have been investigated.In the case of the arabinofuranosides, reproducible acetolysis conditions were obtained by substantially decreasing the amount of sulphuric acid with respect to acetic acid-acetic anhydride mixtures.With the ribofuranosides low temperature acetolysis for a short time resulted in good isolated yield of the β-1-O-acetyl anomer.
