98879-33-5

Upstream product

• 5720-05-8 4-methylphenylboronic acid 
• 3958-03-0 Tetrabromothiophene 
• 106-38-7 para-bromotoluene 
• 88-13-1 3-Thiophene carboxylic acid 
• 825-44-5 benzothiophene-1,1-dioxide 
• 906482-67-5 tetrakis(4-methylphenyl)thiophene S-oxide 
• 2789-88-0 1,2-bis(4-methylphenyl)acetylene 

Relevant academic research and scientific papers

Accessing π-expanded heterocyclics beyond dibenzothiophene: Syntheses and properties of phenanthrothiophenes

A series of phenanthrothiophenes are designed and synthesized from polyarylthiophenes through regioselective Scholl reactions in one step using iron chloride as catalyst. The molecular structures of these heteroarenes displayed multiple twisted fjords, which perturb the shapes of the polycyclic frameworks to pack in slipped to near-perfect face-to-face styles in parallel or antiparallel packings. Field-effect transistor devices using single crystals of 6,12-difluorodiphenanthro[9, 10-b:9′, 10′]thiophene gave a hole mobility of 0.22 cm2 V?1 s?1.

Trisulfur Radical Anion (S3?-) Involved [1 + 2 + 2] and [1 + 3 + 1] Cycloaddition with Aromatic Alkynes: Synthesis of Tetraphenylthiophene and 2-Benzylidenetetrahydrothiophene Derivatives

S3?--mediated [1 + 2 + 2] and [1 + 3 + 1] cycloaddition reactions of aromatic alkynes to give tetraphenylthiophene and 2-benzylidenetetrahydrothiophene derivatives via two C-S bond formations are developed. These two protocols provide new, simple, and straightforward strategies to construct tetraphenylthiophene and 2-benzylidenetetrahydrothiophene derivatives under transition-metal-free conditions. This study also expands the application of S3?- in organic reactions.

Regioselective palladium(0)-catalyzed cross-coupling reactions and metal-halide exchange reactions of tetrabromothiophene: Optimization, scope and limitations

The Suzuki reaction of tetrabromothiophene with arylboronic acids provides a regioselective approach to various 5-aryl-2,3,4-tribromothiophenes, symmetrical 2,5-diaryl-3,4-dibromothiophenes, and tetraarylthiophenes. Unsymmetrical 2,5-diaryl-3,4-dibromo thiophenes are prepared by Suzuki reaction of 5-aryl-2,3,4-tribromothiophenes. Tetraarylthiophenes containing two different types of aryl groups are obtained by Suzuki reactions of 2,5-diaryl-3,4- dibromothiophenes. During the optimization of the conditions of each individual reaction, the solvent, the catalyst and the temperature play an important role. In several cases, classical conditions.

Cycloaddition of benzo[b]thiophene-S,S-dioxide - A route to substituted dibenzothiophenes and dibenzothiophene S,S-dioxides

Benzo[b]thiophene S,S-dioxide can be transformed by cycloaddition with tetraarylthiophene S-oxides to tetraaryldibenzothiophene S,S-dioxides. An analogous cycloaddition of benzo[b]thiophene S,S-dioxide, albeit at higher temperatures, leads directly to tet

Palladium-catalyzed perarylation of 3-thiophene- and 3-furancarboxylic acids accompanied by C-H bond cleavage and decarboxylation

3-Thiophene- and 3-furancarboxylic acids efficiently undergo perarylation accompanied by cleavage of the three C-H bonds and decarboxylation upon treatment with excess aryl bromides in the presence of a palladium catalyst to give the corresponding tetraarylated products in good yields.

Synthesis of tetraarylthiophenes by regioselective Suzuki cross-coupling reactions of tetrabromothiophene

Tetraarylthiophenes were prepared by regioselective Suzuki cross-coupling reactions of tetrabromothiophene.