98892-64-9Relevant academic research and scientific papers
Evidence for Ambivalent Azomethine Ylide Intermediate in the 1,3-Cycloaddition of Trimethylsilyl-methylamine Derivatives
Terao, Yoshiyasu,Imai, Nobuyuki,Achiwa, Kazuo
, p. 1596 - 1598 (2007/10/02)
Evidence for an ambivalent azomethine ylide intermediate was provided by the 1,3-cycloaddition of deuterated N-benzyl-N-(methoxymethyl)trimethylsilylmethylamine to dimethyl benzylidene malonate and related reactions.Keywords: azomethine ylide; 1,3-cycloaddition; ambivalence; N-benzyl-N-(methoxymethyl)trimethylsilylmethylamine; tetrabutylammonium fluoride
A DEFINITE EVIDENCE ON THE AMBIVALENT AZOMETHINE YLIDE INTERMEDIATE IN TRIFLUOROACETIC ACID- AND FLUORIDE ANION-PROMOTED 1,3-CYCLOADDITIONS INVOLVING THE SILICON-CARBON BOND CLEAVAGE
Terao, Yoshiyasu,Kotaki, Hiromi,Imai, Nobuyuki,Achiwa, Kazuo
, p. 896 - 898 (2007/10/02)
Trifluoroacetic acid- and fluoride anion-promoted 1,3-cycloadditions of N-benzyl-N-(methoxymethyl)trimethylsilylmethylamine to dipolarophiles were found to proceed via the ambivalent azomethine ylide intermediates.KEYWORDS - azomethine ylide; 1,3-cycloaddition; ambivalence; N-benzyl-N-(methoxymethyl)trimethylsilylmethylamine; dipolarophile
