98899-77-5Relevant academic research and scientific papers
Silver-catalyzed cross-coupling reactions of alkyl bromides with alkyl or aryl Grignard reagents
Someya, Hidenori,Yorimitsu, Hideki,Oshima, Koichiro
supporting information; experimental part, p. 3270 - 3272 (2009/08/09)
Treatment of secondary or tertiary alkyl bromides with alkyl Grignard reagents in the presence of catalytic amounts of silver bromide and potassium fluoride in CH2Cl2 afforded the corresponding cross-coupling products in reasonable yields. Moreover, silver showed catalytic activity for the cross-coupling reactions of alkyl bromides with aryl Grignard reagents.
