98909-91-2Relevant academic research and scientific papers
METHOD FOR PRODUCING CARBONYL COMPOUND AN PRO-OXIDANT USED FOR PRODUCTION OF CARBONYL COMPOUND
-
Page/Page column 13; 14-15, (2009/08/16)
The invention provides a process for the preparation of a carbonyl compound in high efficiency by oxidizing an alcohol. The process for the preparation of a carbonyl compound of the present invention includes a step of oxidizing an alcohol in the presence of a compound of the formula (I) or a derivative or a salt thereof, and an oxidant, wherein R1 and R2 independently represent hydrogen, a halogen, a nitro or acidic group, or an alkyl or alkoxy group, each of which optionally has a substituent, or R1 and R2 combine the two carbon atoms to which they are boned to form an aromatic ring.
Addition of Aldehydes to Activated Double Bonds, XXXVI. Syntheses and Reactions of 3-Acyl-1,5-dicarbonyl Compounds
Stetter, Hermann,Simons, Leo
, p. 3172 - 3187 (2007/10/02)
Thiazolium salt-catalyzed addition of aldehydes to the 2-methylene-1,4-ketoketals 6-10 and to the unsaturated 2-(alkoxycarbonyl)-1,5-ketoketals 21-24 leads to 3-acyl-1,5-dicarbonyl compounds 30-41.Furthermore, the 4- and 5-(2-oxoalkyl)-2-cyclopenten-1-one
