98929-27-2Relevant academic research and scientific papers
UNTERSUCHUNGEN AN DIAZOVERBIDUNGEN UND AZIDEN-LVII TRI- UND TETRACYCLEN AUS 5-(DIAZOMETHYL)-5H-BENZOCYCLOHEPTENEN UND 4-PHENYL-1,2,4-TRIAZOLIN-3,5-DION
Boehshar, M.,Maas, G.,Heydt, H.,Regitz, M.
, p. 825 - 835 (1985)
The phosphoryl diazomethanes 10a and b undergo electrophilic diazoalkane substitution with the 7-alkylthio benzocycloheptenylium perchlorates 9a and b to the 5-(diazomethyl)-5H-benzocycloheptenes 11a-d.Even the non-dissociated 7 is suited for such a subst
