98977-56-1Relevant academic research and scientific papers
A non-heme iron(III) complex with porphyrin-like properties that catalyzes asymmetric epoxidation
Niwa, Takashi,Nakada, Masahisa
supporting information; experimental part, p. 13538 - 13541 (2012/10/08)
In this report, we describe an iron(III) complex containing a carbazole-based tridentate ligand that catalyzes highly enantioselective asymmetric epoxidation of (E)-alkenes at room temperature. The non-heme iron(III) complex has a five-coordinated trigonal-bipyramidal structure, and its two-electron oxidized state has the similar electronic structure as that of iron porphyrins.
Bicyclic allylether derivatives, processes for their production and their use
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, (2008/06/13)
Compounds of formula I STR1 wherein R1 represents a group of formula STR2 whereby R4 and R5 are the same or different and represent hydrogen, halogen, lower alkyl, lower alkoxy or trifluoromethyl and X represents oxygen, sulfur, imino, lower alkylimino, --(CH2)--, --(S.CH2)-- or --(O.CH2)--, R2 represents hydrogen or lower alkyl, R3 represents a group of formula STR3 whereby R6, R7 and R8 are the same or different and represent hydrogen or alkyl or R6 together with R7 or R7 together with R8 represent --(CH2)m -- wherein m is 3 to 6, R9 represents alkyl, alkenyl, trialkylsilyl or alkyl substituted by hydroxy, lower alkoxy, lower halogenalkyl or aryl and n stands for 1, 2 or 3, which possess pharmaceutical in particular antimycotic activity as well as activity against phytopathogenic fungi.
